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主动式队列管理;传输控制协议;往返时滞;史密斯预估器 1

二氧化碳捕集 1

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聚乙烯胺促进传递膜用于燃烧后二氧化碳捕集——从材料到工艺的挑战和前景 Perspective

何雪忠

《工程(英文)》 2021年 第7卷 第1期   页码 124-131 doi: 10.1016/j.eng.2020.11.001

摘要:

由于气体分离膜具有高能效、相对较低的成本和环境影响,通过气体分离膜捕集二氧化碳(CO2)变得越来越具有吸引力。在过去的十年中,人们开发了基于聚乙烯胺(PVAm)的促进传递(FT)膜来捕集CO2。本文讨论了聚乙烯胺促进传递膜应用于发电厂和水泥厂的燃烧后CO2捕集从材料到工艺的挑战。我们可以基于先前中试示范中获得的经验来指导设计其他类型的膜捕集CO2。特别强调了组件和工艺设计对实现高性能膜系统的重要性。此外,过程模拟和成本估算的结果表明,三级膜系统对于实现95%的高CO2纯度是可行的。我们发现单位CO2的捕集成本在很大程度上取决于所需的CO2捕集率,在50%的中等CO2捕集率下,捕集每吨CO2的成本为63.7美元。因此,我们发现FT膜系统对于部分CO2捕集更具竞争力。

关键词: 促进传递膜     烟道气排放     中空纤维     二氧化碳捕集     过程模拟    

Simultaneous Feammox and anammox process facilitated by activated carbon as an electron shuttle for autotrophic

《环境科学与工程前沿(英文)》 2022年 第16卷 第7期 doi: 10.1007/s11783-021-1498-z

摘要:

• The autotrophic nitrogen removal combining Feammox and Anammox was achieved.

关键词: Feammox     Anammox     Extracellular electron transfer     Electron shuttle     Activated carbon    

A ternary mechanism for the facilitated transfer of metal ions onto metal–organic frameworks: implications

《化学科学与工程前沿(英文)》   页码 1632-1642 doi: 10.1007/s11705-022-2187-6

摘要: Although metal–organic frameworks offer a new platform for developing versatile sorption materials, yet coordinating the functionality, structure and component of these materials remains a great challenge. It depends on a comprehensive knowledge of a “real sorption mechanism”. Herein, a ternary mechanism for U(VI) uptake in metal–organic frameworks was reported. Analogous MIL-100s (Al, Fe, Cr) were prepared and studied for their ability to sequestrate U(VI) from aqueous solutions. As a result, MIL-100(Al) performed the best among the tested materials, and MIL-100(Cr) performed the worst. The nuclear magnetic resonance technique combined with energy-dispersive X-ray spectroscopy and zeta potential measurement reveal that U(VI) uptake in the three metal–organic frameworks involves different mechanisms. Specifically, hydrated uranyl ions form outer-sphere complexes in the surface of MIL-100s (Al, Fe) by exchanging with hydrogen ions of terminal hydroxyl groups (Al-OH2, Fe-OH2), and/or, hydrated uranyl ions are bound directly to Al(III) center in MIL-100(Al) through a strong inner-sphere coordination. For MIL-100(Cr), however, the U(VI) uptake is attributed to electrostatic attraction. Besides, the sorption mechanism is also pH and ionic strength dependent. The present study suggests that changing metal center of metal–organic frameworks and sorption conditions alters sorption mechanism, which helps to construct effective metal–organic frameworks-based sorbents for water purification.

关键词: U(VI)     metal–organic frameworks     adsorption mechanism     metal node    

Nucleic acid crystallization and X-ray crystallography facilitated by single selenium atom

Wen Zhang,Jack W. Szostak,Zhen Huang

《化学科学与工程前沿(英文)》 2016年 第10卷 第2期   页码 196-202 doi: 10.1007/s11705-016-1565-3

摘要: X-ray crystallography is a powerful strategy for 3-D structure determination of macromolecules, such as nucleic acids and protein-nucleic acid complexes. However, the crystallization and phase determination are the major bottle-neck problems in crystallography. Recently we have successfully developed synthesis and strategy of selenium-derivatized nucleic acids (SeNA) for nucleic acid crystallography. SeNA might not only provide the rational strategies to solve the phase determination problem, but also offer a potential strategy to explore crystallization solutions.

关键词: selenium     DNA     RNA     nucleic acid     crystallization    

Decontamination of Cr(VI) facilitated formation of persistent free radicals on rice husk derived biochar

Kaikai Zhang, Peng Sun, Yanrong Zhang

《环境科学与工程前沿(英文)》 2019年 第13卷 第2期 doi: 10.1007/s11783-019-1106-7

摘要:

PFRs were produced on biochar during Cr(VI) decontamination.

PFRs formation on biochar was owing to the oxidization of phenolic-OH by Cr(VI).

Appearance of excessive oxidant led to the consumption of PFRs on biochar.

Biochar charred at high temperature possessed great performance to Cr(VI) removal.

关键词: Biochar     Persistent free radicals     Phenolic hydroxyl groups     Cr(VI) reduction    

The source and transport of bioaerosols in the air: A review

《环境科学与工程前沿(英文)》 2021年 第15卷 第3期 doi: 10.1007/s11783-020-1336-8

摘要:

• Emission of microbe from local environments is a main source of bioaerosols.

关键词: Bioaerosols     Diffusion     Source identification     Biogeography    

Intercontinental transport of air pollution

Lin ZHANG,

《环境科学与工程前沿(英文)》 2010年 第4卷 第1期   页码 20-29 doi: 10.1007/s11783-010-0014-7

摘要: There is an increasing interest on the intercontinental transport of air pollution among the three main emission regions at northern mid-latitudes: North America, Europe, and East Asia. Air pollutants with sufficient long lifetime can be transported from one continent to another. Observations from ground sites, aircraft and satellites have demonstrated this intercontinental-scale transport of air pollutants in the free troposphere. Numerical models have been applied to understand the pathways of the transport and the impact of intercontinental pollution transport. This paper reviews current observational evidence and modeling studies of intercontinental transport of ozone and its precursors, and the resulting impacts on air quality.

关键词: intercontinental transport     ozone     air pollution    

Future urban transport management

《工程管理前沿(英文)》   页码 534-539 doi: 10.1007/s42524-023-0255-3

摘要: The incorporation of disruptive innovations into the transportation industry will inevitably cause major upheavals in the transportation sector. However, existing research lacks systematic theories and methodologies to represent the underlying characteristics of future urban transport systems. Furthermore, emerging modes in urban mobility have not been sufficiently studied. The National Natural Science Foundation of China (NSFC) officially approved the Basic Science Center project titled “Future Urban Transport Management” in 2022. The project members include leading scientists and engineers from Beijing Jiaotong University, Beihang University, and Beijing Transport Institute. Based on a wide range of previous projects by the consortium on urban mobility and sustainable cities, this project will encompass transdisciplinary and interdisciplinary research to explore critical issues affecting future urban traffic management. It aims to develop fundamental theories and methods based on social and technological developments in the near future and explores innovative solutions to implement alongside these emerging developments in urban mobility.

关键词: future urban transport management     travel behavior characteristics     transportation operations     transportation emergency management     transportation decision intelligence    

Thermal transport properties of monolayer phosphorene: a mini-review of theoretical studies

Guangzhao QIN, Ming HU

《能源前沿(英文)》 2018年 第12卷 第1期   页码 87-96 doi: 10.1007/s11708-018-0513-y

摘要: Phosphorene, a two-dimensional (2D) elemental semiconductor with a high carrier mobility and intrinsic direct band gap, possesses fascinating chemical and physical properties distinctively different from other 2D materials. Its rapidly growing applications in nano-/opto-electronics and thermoelectrics call for fundamental understanding of the thermal transport properties. Considering the fact that there have been so many studies on the thermal transport in phosphorene, it is on emerging demand to have a review on the progress of previous studies and give an outlook on future work. In this mini-review, the unique thermal transport properties of phosphorene induced by the hinge-like structure are examined. There exists a huge deviation in the reported thermal conductivity of phosphorene in literature. Besides, the mechanism underlying the deviation is discussed by reviewing the effect of different functionals and cutoff distance in calculating the thermal transport properties of phosphorene. It is found that the (vdW) interactions play a key role in the formation of resonant bonding, which leads to long-ranged interactions. Taking into account of the vdW interactions and including the long-ranged interactions caused by the resonant bonding with large cutoff distance are important for getting the accurate and converged thermal conductivity of phosphorene. Moreover, a fundamental insight into the thermal transport is provided based on the review of resonant bonding in phosphorene. This mini-review summarizes the progress of the thermal transport in phosphorene and gives an outlook on future horizons, which would benefit the design of phosphorene based nano-electronics.

关键词: thermal transport     phosphorene     resonant bonding    

EFFECTS OF TRANSPORT STRESS ON THE INTESTINES INVOLVING NEURONAL NITRIC OXIDE SYNTHASE

《农业科学与工程前沿(英文)》   页码 285-295 doi: 10.15302/J-FASE-2022469

摘要:

● Transport stress declined the level of leukocytes including lymphocytes in rat serum.

关键词: intestine     nNOS     nNOS-positive neurons     transport stress    

Chinmedomics facilitated quality-marker discovery of Sijunzi decoction to treat spleen qi deficiency

Qiqi Zhao, Xin Gao, Guangli Yan, Aihua Zhang, Hui Sun, Ying Han, Wenxiu Li, Liang Liu, Xijun Wang

《医学前沿(英文)》 2020年 第14卷 第3期   页码 335-356 doi: 10.1007/s11684-019-0705-9

摘要: Sijunzi decoction (SJZD) is a Chinese classical formula to treat spleen qi deficiency syndrome (SQDS) and has been widely used for thousands of years. However, the quality control (QC) standards of SJZD are insufficient. Chinmedomics has been designed to discover and verify bioactive compounds of a variety of formula rapidly. In this study, we used Chinmedomics to evaluate the SJZD’s efficacy against SQDS to discover the potential quality-markers (q-markers) for QC. A total of 56 compounds in SJZD were characterized , and 23 compounds were discovered . A total of 58 biomarkers were related to SQDS, and SJZD can adjust a large proportion of marker metabolites to normal level and then regulate the metabolic profile to the health status. A total of 10 constituents were absorbed as effective ingredients that were associated with overall efficacy. We preliminarily determined malonyl-ginsenoside Rb2 and ginsenoside Ro as the q-markers of ginseng; dehydrotumulosic acid and dihydroxy lanostene-triene-21-acid as the q-markers of poria; glycyrrhizic acid, isoglabrolide, and glycyrrhetnic acid as the q-markers of licorice; and 2-atractylenolide as the q-marker of macrocephala. According to the discovery of the SJZD q-markers, we can establish the quality standard that is related to efficacy.

关键词: traditional Chinese medicine     Sijunzi decoction     spleen qi deficiency syndrome     Chinmedomics     quality-marker    

Cooling strategies and transport theories for brain hypothermia resuscitation

LIU Jing

《能源前沿(英文)》 2007年 第1卷 第1期   页码 32-57 doi: 10.1007/s11708-007-0004-z

摘要: The brain is one of the most important organs in a biological body whose normal function depends heavily on an uninterrupted delivery of oxygen. Unlike skeletal muscles that can survive for hours without oxygen, neuron cells in the brain are easily subjected to an irreversible damage within minutes from the onset of oxygen deficiency. With the interruption of cardiopulmonary circulation in many cardiac surgical procedures or accidental events leading to cerebral circulation arrest, an imbalance between energy production and consumption will occur which causes a rapid depletion of oxygen due to the interrupted blood-flow to the brain. Meanwhile, the cooling function of the blood flow on the hot tissue will be stopped, while metabolic heat generation in the tissues still keeps running for awhile. Under such adverse situations, the potential for cerebral protection through hypothermia has been intensively investigated in clinics by lowering brain temperature to restrain the cerebral oxygen demands. The reason can be attributed to the decreased metabolic requirements of the cold brain tissues, which allows a longer duration for the brain to endure reduced oxygen delivery. It is now clear that hypothermia would serve as the principal way for neurologic protection in a wide variety of emergency medicines, especially in cerebral damage, anoxia, circulatory arrest, respiratory occlusion, etc. However, although brain cooling has been found uniquely significant in clinical practices, the serious lack of knowledge on the mechanisms involved prevents its further advancement in brain resuscitation. Compared with the expanded trials in clinics, only very limited efforts were made to probe the engineering issues involved, which turns out to be a major obstacle for the successful operation of brain hypothermia resuscitation. From the viewpoint of biothermal medical engineering, the major theories and strategies for administering brain cooling can generally be classified into three categories: heat transfer, oxygen transport and cooling strategy. Aiming to provide a complete overview of the brain hypothermia resuscitation, this article comprehensively summarizes the recent progresses made in theoretical, practical and experimental techniques in the area. Particularly, attention is paid to the mathematical models to quantify the heat and oxygen transport inside the cerebral tissues. Typical cooling strategies to effectively lower brain temperature and thus decrease oxygen consumption rate in the cerebral tissues are analyzed. Approaches to deliver oxygen directly to the target tissues are discussed. Meanwhile, some future efforts worth pursuing within the area of brain cooling are suggested.

关键词: mathematical     interruption     hypothermia     metabolic     generation    

Seasonal variations of transport pathways andpotential sources of PM

Yuan Chen, Shaodong Xie, Bin Luo

《环境科学与工程前沿(英文)》 2018年 第12卷 第1期 doi: 10.1007/s11783-018-1009-z

摘要: Seasonal pattern of transport pathways and potential sourcesof PM in Chengdu during 2012–2013were investigated based on hourly PM data,backward trajectories, clustering analysis, potential source contributionfunction (PSCF), and concentration-weighted trajectory (CWT) method.The annual hourly mean PM concentrationin Chengdu was 97.4 mg·m . 5, 5, 5 and 3 mean clusters were generatedin four seasons, respectively. Short-distance air masses, which travelledwithin the Sichuan Basin with no specific source direction and relativelyhigh PM loadings (>80 mg·m ) appearedas important pathways in all seasons. These short pathways indicatedthat emissions from both local and surrounding regions of Chengducontributed significantly to PM pollution.The cities in southern Chengdu were major potential sources with PSCF>0.6and CWT>90 mg·m . The northeastern pathway prevailed throughoutthe year with higher frequency in autumn and winter and lower frequencyin spring and summer. In spring, long-range transport from southernXinjiang was a representative dust invasion path to Chengdu, and theCWT values along the path were 30-60 mg·m . Long-range transportwas also observed in autumn from southeastern Xinjiang along a northwesterlypathway, and in winter from the Tibetan Plateau along a westerly pathway.In summer, the potential source regions of Chengdu were smaller thanthose in other seasons, and no long-range transport pathway was observed.Results of PSCF and CWT indicated that regions in Qinghai and Tibetcontributed to PM pollution in Chengdu aswell, and their CWT values increased to above 30 mg·m in winter.

关键词: Transport pathway     Backwardtrajectory     Clustering analysis     Potential source     Chengdu    

A CFD study of the transport and fate of airborne droplets in a ventilated office: The role of droplet

《环境科学与工程前沿(英文)》 2022年 第16卷 第3期 doi: 10.1007/s11783-021-1465-8

摘要:

• Coulomb and Lennard−Jones forces were considered for droplet interactions.

关键词: Droplet interactions     Aerosols     Colloids     CFD     Transport     Fate    

Computational fluid dynamics simulation of aerosol transport and deposition

Yingjie TANG, Bing GUO

《环境科学与工程前沿(英文)》 2011年 第5卷 第3期   页码 362-377 doi: 10.1007/s11783-011-0365-8

摘要: In this article computational fluid dynamics (CFD) simulation of aerosol transport and deposition, i.e. the transport and deposition of particles in an aerosol, is reviewed. The review gives a brief account of the basics of aerosol mechanics, followed by a description of the general CFD approach for flow field simulation, turbulence modeling, wall treatments and simulation of particle motion and deposition. Then examples from the literature are presented, including CFD simulation of particle deposition in human respiratory tract and particle deposition in aerosol devices. CFD simulation of particle transport and deposition may provide information that is difficult to obtain through physical experiments, and it may help reduce the number of experiments needed for device design. Due to the difficulty of describing turbulent flow and particle-eddy interaction, turbulent dispersion of particles remains one of the greatest challenges for CFD simulation. However, it is possible to take a balanced approach toward quantitative description of aerosol dispersion using CFD simulation in conjunction with empirical relations.

关键词: computational fluid dynamics (CFD)     aerosol     transport     deposition    

标题 作者 时间 类型 操作

聚乙烯胺促进传递膜用于燃烧后二氧化碳捕集——从材料到工艺的挑战和前景

何雪忠

期刊论文

Simultaneous Feammox and anammox process facilitated by activated carbon as an electron shuttle for autotrophic

期刊论文

A ternary mechanism for the facilitated transfer of metal ions onto metal–organic frameworks: implications

期刊论文

Nucleic acid crystallization and X-ray crystallography facilitated by single selenium atom

Wen Zhang,Jack W. Szostak,Zhen Huang

期刊论文

Decontamination of Cr(VI) facilitated formation of persistent free radicals on rice husk derived biochar

Kaikai Zhang, Peng Sun, Yanrong Zhang

期刊论文

The source and transport of bioaerosols in the air: A review

期刊论文

Intercontinental transport of air pollution

Lin ZHANG,

期刊论文

Future urban transport management

期刊论文

Thermal transport properties of monolayer phosphorene: a mini-review of theoretical studies

Guangzhao QIN, Ming HU

期刊论文

EFFECTS OF TRANSPORT STRESS ON THE INTESTINES INVOLVING NEURONAL NITRIC OXIDE SYNTHASE

期刊论文

Chinmedomics facilitated quality-marker discovery of Sijunzi decoction to treat spleen qi deficiency

Qiqi Zhao, Xin Gao, Guangli Yan, Aihua Zhang, Hui Sun, Ying Han, Wenxiu Li, Liang Liu, Xijun Wang

期刊论文

Cooling strategies and transport theories for brain hypothermia resuscitation

LIU Jing

期刊论文

Seasonal variations of transport pathways andpotential sources of PM

Yuan Chen, Shaodong Xie, Bin Luo

期刊论文

A CFD study of the transport and fate of airborne droplets in a ventilated office: The role of droplet

期刊论文

Computational fluid dynamics simulation of aerosol transport and deposition

Yingjie TANG, Bing GUO

期刊论文